高級氧化—鐵碳微電解處理某化學合成制藥廢水案例

摘要: 摘(zhai)要(yao)：化(hua)(hua)(hua)學(xue)合(he)成(cheng)(cheng)制(zhi)藥(yao)廢(fei)水(shui)(shui)(shui)(shui)(shui)(shui)(shui)生(sheng)(sheng)物毒性(xing)大、可(ke)生(sheng)(sheng)化(hua)(hua)(hua)性(xing)差，屬高(gao)濃度(du)難降解(jie)有機(ji)廢(fei)水(shui)(shui)(shui)(shui)(shui)(shui)(shui)，采用(yong)(yong)高(gao)級(ji)氧(yang)化(hua)(hua)(hua)-鐵碳微(wei)電解(jie)-ABR—UBF-好氧(yang)工(gong)藝進(jin)行處理，工(gong)程實(shi)踐表明(ming)，該工(gong)藝處理效果穩定可(ke)靠，出(chu)水(shui)(shui)(shui)(shui)(shui)(shui)(shui)COD在300mg/L以下，出(chu)水(shui)(shui)(shui)(shui)(shui)(shui)(shui)水(shui)(shui)(shui)(shui)(shui)(shui)(shui)質完(wan)全達到污(wu)(wu)水(shui)(shui)(shui)(shui)(shui)(shui)(shui)綜合(he)排放(fang)標(biao)準(GB8978—1996)中二級(ji)排放(fang)標(biao)準. 關鍵詞：制(zhi)藥(yao)廢(fei)水(shui)(shui)(shui)(shui)(shui)(shui)(shui)；高(gao)級(ji)氧(yang)化(hua)(hua)(hua)；鐵碳微(wei)電解(jie)；ABR；UBF 河南某藥(yao)業股份(fen)有限公司合(he)成(cheng)(cheng)分廠采用(yong)(yong)化(hua)(hua)(hua)學(xue)合(he)成(cheng)(cheng)法生(sheng)(sheng)產(chan)克林霉素、阿(a)奇霉素、左氧(yang)氟沙星等抗生(sheng)(sheng)素。其生(sheng)(sheng)產(chan)廢(fei)水(shui)(shui)(shui)(shui)(shui)(shui)(shui)可(ke)分為高(gao)濃度(du)廢(fei)水(shui)(shui)(shui)(shui)(shui)(shui)(shui)和低濃度(du)廢(fei)水(shui)(shui)(shui)(shui)(shui)(shui)(shui)，高(gao)濃度(du)廢(fei)水(shui)(shui)(shui)(shui)(shui)(shui)(shui)主要(yao)為生(sheng)(sheng)產(chan)車間用(yong)(yong)于合(he)成(cheng)(cheng)藥(yao)劑(ji)時產(chan)生(sheng)(sheng)的(de)廢(fei)水(shui)(shui)(shui)(shui)(shui)(shui)(shui)，其抗生(sheng)(sheng)素含量高(gao)、生(sheng)(sheng)物毒性(xing)大、可(ke)生(sheng)(sheng)化(hua)(hua)(hua)性(xing)差；低濃度(du)廢(fei)水(shui)(shui)(shui)(shui)(shui)(shui)(shui)主要(yao)為生(sheng)(sheng)產(chan)工(gong)藝過(guo)程中產(chan)生(sheng)(sheng)的(de)大量沖洗廢(fei)水(shui)(shui)(shui)(shui)(shui)(shui)(shui)、污(wu)(wu)冷凝(ning)水(shui)(shui)(shui)(shui)(shui)(shui)(shui)、冷卻排水(shui)(shui)(shui)(shui)(shui)(shui)(shui)以及生(sheng)(sheng)活(huo)污(wu)(wu)水(shui)(shui)(shui)(shui)(shui)(shui)(shui)等。通過(guo)對(dui)企業生(sheng)(sheng)產(chan)的(de)產(chan)品類型及生(sheng)(sheng)產(chan)工(gong)藝分析，決(jue)定采用(yong)(yong)高(gao)級(ji)氧(yang)化(hua)(hua)(hua)-鐵碳微(wei)電解(jie)-ABR-UBF-好氧(yang)工(gong)藝對(dui)該企業的(de)化(hua)(hua)(hua)學(xue)合(he)成(cheng)(cheng)制(zhi)藥(yao)廢(fei)水(shui)(shui)(shui)(shui)(shui)(shui)(shui)進(jin)行處理。出(chu)水(shui)(shui)(shui)(shui)(shui)(shui)(shui)水(shui)(shui)(shui)(shui)(shui)(shui)(shui)質執(zhi)行污(wu)(wu)水(shui)(shui)(shui)(shui)(shui)(shui)(shui)綜合(he)排放(fang)標(biao)準(GB8978—1996)二級(ji)排放(fang)標(biao)準。  

摘要：化(hua)學合(he)(he)成制藥廢水生物毒性(xing)大、可生化(hua)性(xing)差，屬(shu)高(gao)濃(nong)度難降解有(you)機(ji)廢水，采用高(gao)級(ji)氧(yang)化(hua)-鐵碳微電解-ABR—UBF-好(hao)氧(yang)工(gong)藝進行(xing)處(chu)理，工(gong)程實踐表(biao)明，該工(gong)藝處(chu)理效(xiao)果(guo)穩定可靠，出(chu)(chu)水COD在300mg/L以(yi)下，出(chu)(chu)水水質完全達(da)到污水綜合(he)(he)排放(fang)標(biao)準(GB8978—1996)中二級(ji)排放(fang)標(biao)準.

關鍵詞：制藥(yao)廢(fei)水(shui)；高級氧(yang)化；鐵碳微電(dian)解；ABR；UBF

河南某(mou)藥(yao)業(ye)股(gu)份有限(xian)公司合成分(fen)廠采用(yong)化學(xue)合成法(fa)生(sheng)(sheng)(sheng)產(chan)(chan)克林霉(mei)(mei)素、阿奇霉(mei)(mei)素、左氧氟(fu)沙星等抗(kang)(kang)生(sheng)(sheng)(sheng)素。其生(sheng)(sheng)(sheng)產(chan)(chan)廢水(shui)(shui)(shui)可(ke)分(fen)為(wei)高(gao)(gao)濃(nong)度廢水(shui)(shui)(shui)和低(di)濃(nong)度廢水(shui)(shui)(shui)，高(gao)(gao)濃(nong)度廢水(shui)(shui)(shui)主(zhu)要為(wei)生(sheng)(sheng)(sheng)產(chan)(chan)車間用(yong)于合成藥(yao)劑時產(chan)(chan)生(sheng)(sheng)(sheng)的(de)(de)(de)廢水(shui)(shui)(shui)，其抗(kang)(kang)生(sheng)(sheng)(sheng)素含量高(gao)(gao)、生(sheng)(sheng)(sheng)物(wu)毒(du)性(xing)大(da)、可(ke)生(sheng)(sheng)(sheng)化性(xing)差；低(di)濃(nong)度廢水(shui)(shui)(shui)主(zhu)要為(wei)生(sheng)(sheng)(sheng)產(chan)(chan)工藝過程(cheng)中產(chan)(chan)生(sheng)(sheng)(sheng)的(de)(de)(de)大(da)量沖(chong)洗廢水(shui)(shui)(shui)、污冷凝水(shui)(shui)(shui)、冷卻(que)排(pai)水(shui)(shui)(shui)以及生(sheng)(sheng)(sheng)活污水(shui)(shui)(shui)等。通過對企業(ye)生(sheng)(sheng)(sheng)產(chan)(chan)的(de)(de)(de)產(chan)(chan)品類型及生(sheng)(sheng)(sheng)產(chan)(chan)工藝分(fen)析，決定采用(yong)高(gao)(gao)級(ji)氧化-鐵碳(tan)微(wei)電解(jie)-ABR-UBF-好氧工藝對該(gai)企業(ye)的(de)(de)(de)化學(xue)合成制藥(yao)廢水(shui)(shui)(shui)進行(xing)處理。出(chu)水(shui)(shui)(shui)水(shui)(shui)(shui)質執(zhi)行(xing)污水(shui)(shui)(shui)綜合排(pai)放標準(zhun)(GB8978—1996)二級(ji)排(pai)放標準(zhun)。

 

聲明：轉載此文是出于傳遞更多信息之目的。若有來源標注錯誤或侵犯了您的合法權益，請作者持權屬證明與本網聯系，我們將及時更正、刪除，謝謝。

  使用微信“掃一掃”功能添加“谷騰環保網”

如果需要了解更加詳細的內容，請點擊下載 2011070704.pdf 
        下載該附件請登錄，如果還不是本網會員，請先注冊